2022

Current status of sol–gel processing of glasses, ceramics, and organic–inorganic hybrids: a brief review
Koichi Kajihara, Kazuyoshi Kanamori, Atsushi Shimojima
J. Ceram. Soc. Jpn., 130, 575-583 (2022)
 


Fluoride Ion-Encapsulated Germoxane Cages Modified with Organosiloxane Chains as Anionic Components of Ionic Liquids
Taiki Hayashi, Nanako Murase, Naoto Sato, Koki Fujino, Natsuhiko Sugimura, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Organometallics, 41, 1454–1463 (2022).


 

Anisotropic Crystal Growth of Layered Nickel Hydroxide along the Stacking Direction Using Amine Ligands
Keisuke Muramatsu, Mina Jimba, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Inorg. Chem., 61, 8490–8497 (2022).
 


 

Graphical abstract: Preparation of mesoporous nitrogen-doped titania comprising large crystallites with low thermal conductivity

Preparation of mesoporous nitrogen-doped titania comprising large crystallites with low thermal conductivity
Yuta Shimasaki, Takamichi Matsuno, Quansheng Guo, Atsushi Shimojima, Hiroaki Wada, Takao Mori, Kazuyuki Kuroda
Nanoscale Adv., 4, 2509–2520 (2022).
 


 

画像に alt 属性が指定されていません。ファイル名: image-14.png

Photomechanical Organosiloxane Films Derived from Azobenzene-Modified Di- and Tri-alkoxysilanes
Takehiro Harigaya, Ryota Kajiya, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
J. Sol–Gel. Sci. Technol., in press.
 


 
機能性材料の創出に向けた酸化物ナノ多孔体の組成・結晶性・細孔構造制御 (特集 セラミックス多孔体の最前線)
Control of the Composition, Crystallinity, and Porous Structure of Nanoporous Oxides for Development of Functional Materials

松野敬成, 和田宏明, 下嶋敦, 森孝雄, 黒田一幸
セラミックス57, 334–337 (2022)
 


2021

Figure

Hydrogen-bonding-induced Layered Assembly of Cage Siloxanes Modified with Diisopropylsilanol Groups
Naoto Sato, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Lett., 50, 1770–1772 (2021).
 


 

Self-Healing Lamellar Silsesquioxane Thin Films
Satoshi Kodama, Yoshiaki Miyamoto, Shun Itoh, Takashi Miyata, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
ACS Appl. Polym. Mater., 3, 4118–4126 (2021).
 


 

One-step Synthesis of Nanoporous Titanosiloxane-based Materials with Isolated Ti Sites using Cage Siloxane as a Building Block
Takuya Hikino, Koki Fujino, Naoto Sato, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Chem. Lett., 50, 1643–1647 (2021).
 


 

Graphical abstract: Variation of counter quaternary ammonium cations of anionic cage germanoxanes as building blocks of nanoporous materials

Variation of Counter Quaternary Ammonium Cations of Anionic Cage Germanoxanes as Building Blocks of Nanoporous Materials
Taiki Hayashi, Naoto Sato, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Dalton Trans., 50, 8497–8505 (2021).
 


 

Hydrolysis of Methoxylated Nickel Hydroxide Leading to Single-Layer Ni(OH)2 Nanosheets
Keisuke Muramatsu, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Inorg. Chem., 60, 7094–7100 (2021).
 


 

Interlayer Silylation of Layered Octosilicate with Organoalkoxysilanes: Effects of Tetrabutylammonium Fluoride as a Catalyst and the Functional Groups of Silanes
Masashi Yatomi, Masakazu Koike, Nadège Rey,Yuki Murakami, Shohei Saito, Hiroaki Wada, Atsushi Shimojima, David Portehault, Sophie Carenco, Clément Sanchez, Carole Carcel, Michel Wong Chi Man, Kazuyuki Kuroda
Eur. J. Inorg. Chem., 2021, 1836–1845 (2021).
 


 

Formation of Closed Pores in Mesoporous Silica Nanoparticles by Hydrothermal Treatment
Eisuke Yamamoto, Lulu Cheng, Tenkai Watanabe, Seiya Mori, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn., 94, 1625–1630 (2021).
 


 

figure

Preparation of Colloidal Monodisperse Hollow Organosiloxane-based Nanoparticles with Double Mesoporous Shell
Tenkai Watanabe, Eisuke Yamamoto, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn., 94, 1602–1608 (2021).
 


 

Preparation of Ordered Nanoporous Indium Tin Oxides with Large Crystallites and Individual Control over Their Thermal and Electrical Conductivities
Yumi Saito, Takamichi Matsuno, Quansheng Guo, Takao Mori, Makoto Kashiwagi, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
ACS Appl. Mater. Interfaces13, 15373–15382 (2021).
 


 

Graphical abstract: Direct bottom-up synthesis of size-controlled monodispersed single-layer magnesium hydroxide nanosheets modified with tripodal ligands

Direct bottom-up synthesis of size-controlled monodispersed single-layer magnesium hydroxide nanosheets modified with tripodal ligands
Keisuke Muramatsu, Yuya Kamiusuki, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Dalton Trans.50, 3121–3126 (2021).
 


 

Preparation of an Ordered Nanoporous Silicone-based Material Using Silica Colloidal Crystals as a Hard Template
Naho Muramoto, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Chem. Lett.50, 1038–1040 (2021).
 


 

Synthesis of Cristobalite Containing Ordered Interstitial Mesopores using Crystallization of Silica Colloidal Crystals
Takamichi Matsuno, Takamichi Nakaya, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Asian J.16, 207–214 (2021).
 



自己修復性層状シロキサン薄膜の設計
宮本佳明, 下嶋敦
New Glass, 36, 13–15 (2021).
 


2020

Preparation of Sub-50 nm Colloidal Monodispersed Hollow Siloxane-Based Nanoparticles with Controlled Shell Structures
Tenkai Watanabe, Eisuke Yamamoto, Saki Uchida, Lulu Cheng, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Langmuir36, 13833–13842 (2020).
 


 

Graphical abstract: Preparation of periodic mesoporous organosilica with large mesopores using silica colloidal crystals as templates

Preparation of Periodic Mesoporous Organosilica with Large Mesopores Using Silica Colloidal Crystals as Templates
Naho Muramoto, Tomoaki Sugiyama, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Nanoscale12, 21155–21164 (2020).
 


 

figure

Preparation of Porous Pentacoordinate Organosilicon Frameworks Using Organoalkoxysilanes and Tris-catechol Linkers
Masaki Naoe, Hiroki Iwashita, Shohei Saito, Masakazu Koike, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Lett.49, 1075–1077 (2020).
 


 

Mesoporous Silica Nanoparticles with Dispersibility in Organic Solvents and Their Versatile Surface Modification
Eisuke Yamamoto, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Langmuir36, 5571–5578 (2020).
 


 

Graphical abstract: Encapsulation of Cu nanoparticles in nanovoids of plate-like silica sodalite through interlayer condensation of Cu2+ ion-exchanged layered silicate RUB-15

Encapsulation of Cu Nanoparticles in Nanovoids of Plate-like Silica Sodalite Through Interlayer Condensation of Cu2+ Ion-exchanged Layered Silicate RUB-15
Masakazu Koike, Rika Sakai, Shinpei Enomoto, Takeshi Mino, Natsuhiko Sugimura, Takahiro Gotoh, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Dalton Trans.49, 8067–8074 (2020).
 


 

Selective Covalent Modification of Layered Double Hydroxide Nanoparticles with Tripodal Ligands on Outer and Interlayer Surfaces
Keisuke Muramatsu, Shiori Hayashi, Yoshiyuki Kuroda, Yuya Oka, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Inorg. Chem.59, 6110–6119 (2020).
 


 

Molecules 25 00524 g002 550

Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials
Atsushi Shimojima, Kazuyuki Kuroda
Molecules25, 524 (2020).
 


 

figure

Inorganic–Organic Hybrid Photomechanical Crystals of Azobenzene-Modified Polyhedral Oligomeric Silsesquioxane (POSS)
Ryota Kajiya, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Chem. Lett.49, 327–329 (2020).
 


2019

Inorganic–Organic Hybrid Photomechanical Crystals Consisting of Diarylethenes and Cage Siloxanes
Ryota Kajiya, Seiya Sakakibara, Hanako Ikawa, Kenji Higashiguchi, Kenji Matsuda, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Chem. Mater.31, 9372–9378 (2019).
 


 

image file: c9sc02773d-f1.tif

Tracking the Rearrangement of Atomic Configurations During the Conversion of FAU Zeolite to CHA Zeolite
Koki Muraoka, Yuki Sada, Atsushi Shimojima, Watcharop Chaikittisilp, Tatsuya Okubo
Chem. Sci.10, 8533–8540(2019).
  


 

Preparation of CO2-adsorbable Amine-functionalized Polysilsesquioxanes Containing Cross-linked Structures without Using Surfactants and Strong Acid or Base Catalysts
Yusaku Sainohira, Koki Fujino, Atsushi Shimojima, Kazuyuki Kuroda, Yoshiro Kaneko
J. Sol-Gel Sci. Technol., 91, 505–513 (2019).
 


 

Graphical abstract: Formation of silicate nanoscrolls through solvothermal treatment of layered octosilicate intercalated with organoammonium ions

Formation of Silicate Nanoscrolls Through Solvothermal Treatment of Layered Octosilicate Intercalated with Organoammonium Ions
Yusuke Asakura, Megumi Sugihara, Takeru Hirohashi, Aya Torimoto, Takuya Matsumoto, Masakazu Koike, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Nanoscale11, 12924–12931 (2019).
 


 

Synthesis of Organosilyl‐Functionalized Cage‐Type Germanoxanes Containing Fluoride Ions
Naoto Sato, Taiki Hayashi, Kazuma Tochigi, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Eur. J.25, 7860–7865 (2019).
 


 

Fabrication of Uniaxially Aligned Silica Nanogrooves with Sub-5 nm Periodicity on Centimeter-Scale Si Substrate Using Poly(dimethylsiloxane) Stamp
Keiya Hirota, Shintaro Hara, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
ACS Nano13, 2795–2803 (2019).
 


 

Synthesis of Polycyclic and Cage Siloxanes by Hydrolysis and Intramolecular Condensation of Alkoxysilylated Cyclosiloxanes
Tomoaki Sugiyama, Hiroya Shiba, Masashi Yoshikawa, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Eur. J.25, 2764–2772 (2019).
 


 

Graphical abstract: Synthesis and crystal structure of double-three ring (D3R)-type cage siloxanes modified with dimethylsilanol groups

Synthesis and Crystal Structure of Double-three Ring (D3R)-type Cage Siloxanes Modified with Dimethylsilanol Groups
Naoto Sato, Kazuma Tochigi, Yoshiyuki kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Dalton Trans.48, 1969–1975 (2019).
 


2018

Preparation of Ordered Mesoporous Au Using Double Gyroid Mesoporous Silica KIT‐6 via a Seed‐mediated Growth Process
Yuta Shimasaki, Masaki Kitahara, Miho Shoji, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Chem. Asian J.13, 3935–3941 (2018).
 


 

Synthesis of Zeolitic Macrocycles Using Site-Selective Condensation of Regioselectively Difunctionalized Cubic Siloxanes
Shohei Saito, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Inorg. Chem.57, 14686–14691 (2018).
 


 

Preparation of Siloxane‐based Microporous Crystal from Hydrogen-Bonded Molecular Crystal of Cage Siloxane
Naoto Sato, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Eur. J.24, 17033–17038 (2018).
 


 

Graphical abstract: Precise size control of layered double hydroxide nanoparticles through reconstruction using tripodal ligands

Precise Size Control of Layered Double Hydroxide Nanoparticles Through Reconstruction Using Tripodal Ligands
Yoshiyuki Kuroda, Yuya Oka, Tadao Yasuda, Tatsuyuki Koichi, Keisuke Muramatsu, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Dalton Trans.47, 12884–12892 (2018).
 


 

figure

Self-Assembly of Cyclohexasiloxanes Possessing Alkoxysilyl Groups and Long Alkyl Chains
Masashi Yoshikawa, Hanako Ikawa, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Lett.47, 1203–1206 (2018).
 


 

Effect of Intercalated Amide Molecules on Interlayer Condensation of Layered Silicate RUB-15
Masakazu Koike, Yusuke Asakura, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Clay Sci., 22, 1–11 (2018).
 


 

figure

Formation of Silica-Organic Hybrid Nanoparticles by Cross-Linking of Ultra-Small Silica Nanoparticles
Shigeru Sakamoto, Koki Fujino, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Lett.47, 1018–1021 (2018).
 


 

figure

Polymerization of Cyclododecasiloxanes with Si–H and Si–OEt Side Groups by the Piers-Rubinsztajn Reaction
Masashi Yoshikawa, Hiroya Shiba, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn.91, 747–753 (2018).
  


 

Formation of Single-Digit Nanometer Scale Silica Nanoparticles by Evaporation-Induced Self-Assembly
Shigeru Sakamoto, Masashi Yoshikawa, Kota Ozawa, Yoshiyuki Kuroda, Atsushi Shimojima, Kazuyuki Kuroda
Langmuir34, 1711–1717 (2018).
 


Transformation of Mesostructured Silica Nanoparticles into Colloidal Hollow Nanoparticles in the Presence of a Bridged-Organosiloxane Shell
Eisuke Yamamoto, Saki Uchida, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Chem. Mater.30, 540–548 (2018).
 


 

Formation of Concentric Silica Nanogrooves Guided by the Curved Surface of Silica Particles
Shintaro Hara, Keiya Hirota, Yuka Tabe, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Langmuir34, 1733–1741 (2018).
 


 

Graphical abstract: In situ synthesis of magnesium hydroxides modified with tripodal ligands in an organic medium

In situ synthesis of magnesium hydroxides modified with tripodal ligands in an organic medium
Keisuke Muramatsu, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Dalton Trans.47, 3074–3083 (2018).
 


2017

Graphical abstract: Synthesis of a 12-membered cyclic siloxane possessing alkoxysilyl groups as a nanobuilding block and its use for preparation of gas permeable membranes

Synthesis of a 12-membered cyclic siloxane possessing alkoxysilyl groups as a nanobuilding block and its use for preparation of gas permeable membranes
Masashi Yoshikawa, Hiroya Shiba, Masakoto Kanezashi, Hiroaki Wada, Atsushi Shimojima, Toshinori Tsuru, Kazuyuki Kuroda
RSC Adv.7, 48683–48691 (2017).
 


 

Spontaneous Crack Healing in Nanostructured Silica-Based Thin Films
Shun Itoh, Satoshi Kodama, Maho Kobayashi, Shintaro Hara, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
ACS Nano11, 10289–10294 (2017).
 


 

Protecting and Leaving Functions of Trimethylsilyl Groups in Trimethylsilylated Silicates for the Synthesis of Alkoxysiloxane Oligomers
Masashi Yoshikawa, Yasuhiro Tamura, Ryutaro Wakabayashi, Misa Tamai, Atsushi Shimojima, Kazuyuki Kuroda
Angew. Chem. Int. Ed.56, 13990–13994 (2017).
  


 

Nanospace-Mediated Self-Organization of Nanoparticles in Flexible Porous Polymer Templates
Yoshiyuki Kuroda, Itaru Muto, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Langmuir33, 9137–9143 (2017).
 


 

figure

Role of Cubic Siloxane Cages in Mesostructure Formation and Photoisomerization of Azobenzene–Siloxane Hybrid
Sufang Guo, Jun Sasaki, Shiho Tsujiuchi, Shintaro Hara, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Chem. Lett.46, 1237–1239 (2017).
 


 

Synthesis of a Single-Crystalline Macroporous Layered Silicate from Macroporous UTL-Type Zeolite and its Accelerated Intercalation
Yusuke Asakura, Naoki Kawaura, Yoshiyuki Kuroda, Masakazu Koike, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Eur. J.23, 11022–11029 (2017).
 


 

Graphical abstract: Topotactic conversion of layered silicate RUB-15 to silica sodalite through interlayer condensation in N-methylformamide

Topotactic Conversion of Layered Silicate RUB-15 to Silica Sodalite through Interlayer Condensation in N-Methylformamide
Masakazu Koike, Yusuke Asakura, Megumi Sugihara, Yoshiyuki Kuroda, Hidehiro Tsuzura, Hiroaki Wada, Atsushi Shimojima, and Kazuyuki Kuroda
Dalton Trans.46, 10232–10239 (2017).
 


 

Preparation of Mesoporous Basic Mixed Metal Oxides through Assembly of Monodispersed Mg-Al Layered Double Hydroxide Nanoparticles
Yuya Oka, Yoshiyuki Kuroda, Takamichi Matsuno, Keigo Kamata, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Eur. J.23, 9362–9368 (2017).
 


 

Graphical abstract: Thickness control of 3-dimensional mesoporous silica ultrathin films by wet-etching

Thickness Control of 3-Dimensional Mesoporous Silica Ultrathin Films by Wet-Etching
Maho Kobayashi, Kyoka Susuki, Tomohiro Otani, Shinpei Enomoto, Haruo Otsuji, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Takayuki Homma, Kazuyuki Kuroda
Nanoscale9, 8321–8329 (2017).
 


 

Formation of Nanogrooves with Sub-5 nm Periodicity Using Local Silicification at the Interspace between a Si Substrate and Lyotropic Liquid Crystals
Shintaro Hara, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
ACS Nano11, 5160–5166 (2017).
 


 

figure

Pore Clogging of Colloidal Mesoporous Silica Nanoparticles for Encapsulating Guest Species
Eisuke Yamamoto, Kouya Nagata, Kenta Onishi, Chihiro Urata, Atsushi Shimojima, Hiroaki Wada, Shinji Takeoka, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn.90, 706–708 (2017).
 


 

Direct Observation of the Outermost Surfaces of Mesoporous Silica Thin Films by High Resolution Ultralow Voltage Scanning Electron Microscopy
Maho Kobayashi, Kyoka Susuki, Haruo Otsuji, Yusuke Sakuda, Shunsuke Asahina, Naoki Kikuchi, Toshiyuki Kanazawa, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Langmuir33, 2148–2156 (2017).
 


 

Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets by Using Tripodal Ligands as One-Size-Fits-All Modifiers
Yoshiyuki Kuroda, Tatsuyuki Koichi, Keisuke Muramatsu, Kazuya Yamaguchi, Noritaka Mizuno, Atsushi Shimojima, Hiroaki Wada, and Kazuyuki Kuroda
Chem. Eur. J.23, 5023–5032 (2017).
 


 

Graphical abstract: Fabrication of colloidal crystals composed of pore-expanded mesoporous silica nanoparticles prepared by a controlled growth method

Fabrication of Colloidal Crystals Composed of Pore-expanded Mesoporous Silica Nanoparticles Prepared by a Controlled Growth Method
Eisuke Yamamoto, Seiya Mori, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Nanoscale9, 2464–2470 (2017).
 



メソポーラスシリカナノ粒子の精密合成 (特集 テンプレートを利用した機能性材料の形態制御)
Precise Synthesis of Mesoporous Silica Nanoparticles

山本瑛祐, 下嶋 敦, 黒田一幸
日本結晶成長学会誌44, 82–87 (2017).



かご状元素ブロックを用いたシロキサン系多孔体の構築
Construction of Siloxane-based Porous Materials by Using Cage-type Element Blocks

佐藤尚人, 和田宏明, 下嶋 敦, 黒田一幸
粉体および粉末冶金64, 126–129 (2017).
 



メソ多孔体薄膜研究の最近の展開 (特集 次代を切り拓く”ゼオライト”の最新技術をさぐる)
原 慎太郎, 下嶋 敦, 黒田一幸
工業材料65, 54–57 (2017).
 



コロイド粒子を用いたシリカメソ多孔体合成の新展開 (特集 セラミックスナノ多孔体)
New Developments in the Synthesis of Mesoporous Silica Materials Using Colloidal Particles

黒田義之, 山本瑛祐, 下嶋 敦, 和田宏明, 黒田一幸
セラミックス52, 3–5 (2017).
 


2016

Selective Formation of Alkoxychlorosilanes and Organotrialkoxysilane with Four Different Substituents by Intermolecular Exchange Reaction
Yuma Komata, Masashi Yoshikawa, Yasuhiro Tamura, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Asian J.11, 3225–3233 (2016).
  


 

figure

Use of Mesoporous Silica Modified with Titanium Oxide as a Template for Preparation of Mesoporous Carbon Incorporating TiO2 Nanocrystals
Masaki Kitahara, Kohei Suzuki, Saori Kubara, Yuta Shimasaki, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn.89, 1207–1211 (2016).
 


 

Cubic Siloxanes with Both Si−H and Si−OtBu Groups for Site-Selective Siloxane Bond Formation
Shohei Saito, Nao Yamasue, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Eur. J.22, 13857–13864 (2016).
 


 

A photoresponsive azobenzene-bridged cubic silsesquioxane network
Sufang Guo, Tatsuya Okubo, Kazuyuki Kuroda, Atsushi Shimojima
J. Sol-Gel Sci. Technol.79, 262–269 (2016).
 


 

Usefulness of Mesoporous Silica as a Template for Preparation of Bundles of Bi Nanowires with Precisely Controlled Diameter below 10 nm
Masaki Kitahara, Hasbuna Kamila, Atsushi Shimojima, Hiroaki Wada, Takao Mori, Ichiro Terasaki, Kazuyuki Kuroda
Chem. Asian J.11, 900–905 (2016).
 


 

A Single-Crystalline Mesoporous Quartz Superlattice
Takamichi Matsuno, Yoshiyuki Kuroda, Masaki Kitahara, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Angew. Chem. Int. Ed.55, 6008–6012 (2016).
 



有機シランを用いた光応答性元素ブロック高分子の作製 (特集 元素ブロック高分子材料 : 高機能材料への新コンセプト)
Preparation of Photoresponsive Element-block Polymers Using Organosilanes

郭 素芳, 松川公洋, 大久保達也, 黒田一幸, 下嶋 敦
セラミックス51, 773–776 (2016).
 


2015

Photoinduced Bending of Self-Assembled Azobenzene–Siloxane Hybrid
Sufang Guo, Kimihiro Matsukawa, Takashi Miyata, Tatsuya Okubo, Kazuyuki Kuroda, Atsushi Shimojima
J. Am. Chem. Soc.137, 15434–15440 (2015).
 


figure

Interlayer Condensation of Protonated Layered Silicate Magadiite through Refluxing in N-Methylformamide
Yusuke Asakura, Nami Hosaka, Shimon Osada, Taichi Terasawa, Atsushi Shimojima, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn.88, 1241–1249 (2015).
 


The Critical Effect of Niobium Doping on the Formation of Mesostructured TiO2: Single-Crystalline Ordered Mesoporous Nb-TiO2 and Plate-like Nb-TiO2 with Ordered Mesoscale Dimples
Masaki Kitahara, Yuta Shimasaki, Takamichi Matsuno, Yoshiyuki Kuroda, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
Chem. Eur. J.21, 13073–13079 (2015).
 


 

Graphical abstract: Regular assembly of cage siloxanes by hydrogen bonding of dimethylsilanol groups

Regular assembly of cage siloxanes by hydrogen bonding of dimethylsilanol groups
Naoto Sato, Yoshiyuki Kuroda, Takuya Abe, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Commun.51, 11034–11037 (2015).
 


 

Graphical abstract: Synthesis of colloidal Janus nanoparticles by asymmetric capping of mesoporous silica with phenylsilsesquioxane

.Synthesis of colloidal Janus nanoparticles by asymmetric capping of mesoporous silica with phenylsilsesquioxane
Hiroto Ujiie, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Commun.51, 3211–3214 (2015).
 


 

figure

Si Substrate as a SiO2 Source for the Preparation of Mesoporous SiO2–TiO2 Thin Films
Shintaro Hara, Hirokatsu Miyata, Masahiko Takahashi, Atsushi Shimojima, Kazuyuki Kuroda
Chem. Lett.44, 372–374 (2015).
  



有機修飾型多孔質シリカナノ粒子の合成と応用 (特集 新しいセラミックス技術開発の展望)
Synthesis and Applications of Organically Modified Porous Silica Nanoparticles

山本瑛祐, 下嶋 敦, 黒田一幸
化學工業66, 376–380 (2015).
  


2014以前代表論文

image

Molecularly Designed Nanoparticles by Dispersion of Self-Assembled Organosiloxane-Based Mesophases
Shigeru Sakamoto, Yasuhiro Tamura, Hideo Hata, Yasuhiro Sakamoto, Atsushi Shimojima, and Kazuyuki Kuroda
Angew. Chem. Int. Ed.53, 9173–9177 (2014).
 


 

Utilization of Alkoxysilyl Groups for the Creation of Structurally Controlled Siloxane-Based Nanomaterials
Kazuyuki Kuroda, Atsushi Shimojima, Kazufumi Kawahara, Ryutaro Wakabayashi, Yasuhiro Tamura, Yusuke Asakura, and Masaki Kitahara
Chem. Mater.26, 211–220 (2014).
* 25-years anniversary SPECIAL ISSUE
  


 

scheme1

Synthesis of mesostructured silica from monoalkyl-substituted double five-ring units
Atsushi Shimojima, Hideki Kuge, and Kazuyuki Kuroda
J. Sol-Gel Sci. Technol.57, 263–268 (2011).
  


 

Effect of organic additives on the formation of alkylsiloxane mesophases
Atsushi Shimojima, Mikako Sakurai, Kazuyuki Kuroda, and Tatsuya Okubo
J. Colloid Interface Sci.350, 155–160 (2010).
 


 

figure

Formation of Reactive Microporous Networks from Alkoxyvinylsilylated Siloxane Cages
Yoshiaki Hagiwara, Atsushi Shimojima, and Kazuyuki Kuroda
Bull. Chem. Soc. Jpn.83, 424–430 (2010).
 


 

Alignment Control of Self-Assembled Organosiloxane Films Derived from Alkyloligosiloxane Amphiphiles
Jenny Du, Madoka Fukushima, Shigeru Sakamoto, Mikako Sakurai, Takashi Suzuki, Atsushi Shimojima, Hirokatsu Miyata, Cathleen M. Crudden, and Kazuyuki Kuroda
Langmuir25, 13614–13618 (2009).
 


Formation of Two- and Three-Dimensional Hybrid Mesostructures from Branched Siloxane Molecules
Shigeru Sakamoto, Atsushi Shimojima, Keiichi Miyasaka, Juanfang Ruan, Osamu Terasaki, and Kazuyuki Kuroda
J. Am. Chem. Soc.131, 9634–9635 (2009).
 


 

Graphical abstract: A hybrid mesoporous material with uniform distribution of carboxy groups assembled from a cubic siloxane-based precursor

A hybrid mesoporous material with uniform distribution of carboxy groups assembled from a cubic siloxane-based precursor
Ryota Goto, Atsushi Shimojima, Hideki Kuge, and Kazuyuki Kuroda
Chem. Commun., 6152–6154 (2008).
 


 

Self-Assembly of Amphiphilic Alkyloligosiloxanes within Cylindrically and Spherically Confined Spaces
Mikako Sakurai, Atsushi Shimojima, Yusuke Yamauchi, and Kazuyuki Kuroda
Langmuir24, 13121–13126 (2008).
 


Self-Assembly of Alkyl-Substituted Cubic Siloxane Cages into Ordered Hybrid Materials
Atsushi Shimojima, Ryota Goto, Norimasa Atsumi, and Kazuyuki Kuroda
Chem. Eur. J.14, 8500–8506 (2008).
 


 

Graphical abstract: Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture

Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture
Kazufumi Kawahara, Yoshiaki Hagiwara, Atsushi Shimojima, and Kazuyuki Kuroda
J. Mater. Chem.18, 3193–3195 (2008).
 


 

Oligomeric Alkoxysilanes with Cagelike Hybrids as Cores: Designed Precursors of Nanohybrid Materials
Hideki Kuge, Yoshiaki Hagiwara, Atsushi Shimojima, and Kazuyuki Kuroda
Chem. Asian J.3, 600–606 (2008).
 


 

Alkoxysilylated-Derivatives of Double-Four-Ring Silicate as Novel Building Blocks of Silica-Based Materials
Yoshiaki Hagiwara, Atsushi Shimojima, and Kazuyuki Kuroda
Chem. Mater.20, 1147–1153 (2008).
 


 

Stable Silanetriols That Contain tert-Alkoxy Groups: Versatile Precursors of Siloxane-Based Nanomaterials
Jumpei Suzuki, Atsushi Shimojima, Yasuhiro Fujimoto, Kazuyuki Kuroda
Chem. Eur. J.14, 973–980 (2008).
 


Book Sections

Siloxane-Based Building Blocks for Molecular Technology
Shohei Saito, Naoto Sato, Masashi Yoshikawa, Atsushi Shimojima, and Kazuyuki Kuroda
Molecular Technology, Volume 4: Synthesis Innovation, John Wiley & Sons, Inc. (2019).
 



Design of Element Blocks for Photoresponsive Organosiloxane-Based Materials
Sufang Guo, Kazuyuki Kuroda, and Atsushi Shimojima
New Polymeric Materials Based on Element-Blocks, Part II Chapter 14, Springer Nature Singapore Pte Ltd. (2019).